When you shower in very hot water the pores of your hair open to receive moisture. Unfortunately, after you step out of the shower, hair absorbs too much moisture and the pores stay open, causing frizzing. Rinsing your hair in cool water closes the hair shaft and makes it less susceptible to frizz, says HairBoutique.com. This method is also applied to styling; once you've finished blowing your hair dry with heat, press down the cool air button and give your hair a final blast to seal in smoothness and lock out excess moisture.
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